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IO3/RXD:D0(Arduino), the RX of Serial, connects to IO3 of ESP32
IO1/TXD:D1(Arduino), the TX of Serial, connects to IO1 of ESP32
IO25/D2:D2 (Arduino) of GPIO digital input and output port and PWM output pin, connect to IO25 of ESP32.
IO26/D3:D3 (Arduino) of GPIO digital input and output port and PWM output pin, connect to IO26 of ESP32.
IO27/D4:D4 (Arduino) of GPIO digital input and output port and PWM output pin, connect to IO27 of ESP32.
IO9/ D5: D5 (Arduino) of GPIO digital input and output port and PWM output pin, connect to IO9 of ESP32.
IO10/D6:D6 (Arduino) of GPIO digital input and output port and PWM output pin, connect to IO9 of ESP32.
IO13/D7:D7 (Arduino) of GPIO digital input and output port and PWM output pin, connect to IO13 of ESP32.
IO5/D8:D8 (Arduino) of GPIO digital input and output port and PWM output pin, connect to IO5 of ESP32.
IO2/D9:D9 (Arduino) of GPIO digital input and output port and PWM output pin, connect to IO2 of ESP32.
CLK:Clock pin to IO6 of ESP32
SD0:SD0 port to IO7 of ESP32
SD1:SD1 port to IO7 of ESP32
CMD:CMD port to IO11 of ESP32
GND:Power line ground
AREF:input voltage for reference, here connect to NC.
3V3:3.3V Vo, can provide 600mA current out at most.
VCC:The Vi/Vo is 5V charged by USB and 3.7V charged by lithium battery.
IO36/A0:A0 (Arduino), analog input, connect to IO36 of ESP32.
IO39/A1:A1 (Arduino), analog input, connect to IO39 of ESP32.
IO34/A2:A2 (Arduino), analog input, connect to IO34 of ESP32.