83 
13.  Installation and Servicing Air Conditioner using R32 
13.1  About R32 Refrigerant 
For air conditioning refrigerants such as R410A, the refrigerants were collected back in order to prevent their air 
dissipation, to curbe the global warming impact, in case they were released into the atmosphere. In the “4th 
Environmental Basic Plan”, 80% reduction of greenhouse gas emissions by 2050 is required, and due to this 
requirement, further reduction in the emission of high greenhouse effect gas, such as CFCs, is required. Therefore, 
the conversion of air conditioning refrigerant into the ones who has smaller greenhouse effect, even if it is dissipated 
into the atmosphere, became our responsibility. 
   
Nevertheless, in case of air conditioning refrigerant, it would be the best if there is a refrigerant which has smaller 
impact on global warming, but ensures good energy efficiency and performance, and is safe; however, there is no 
such refrigerant which satisfies all these conditions. As a result, we have been considering the practical usage, within 
the safety frame-work, of R32 refrigerant which has short lifetime in the atmosphere, and has smaller effect of global 
warming, but is slightly flammable. 
 
In 2004, due to the revision of air conditioner safety standards by the International Electro-safety Commission (IEC), 
the safety standards of air conditioners using slightly flammable refrigerant was issued. In 2010, the regulations of 
American Society of Heating, Refrigerating and Air-Conditioning Engineers in the United States (ANSI/ASHRAE34) 
was issued adopting the grades for refrigerants which are difficult to inflame due to their slow burning rates, and as a 
result have smaller damages in cases of fire. The burning rate of R32 is lower by 10cm / per second, and safety 
standardization for various usage is now being processed. 
13.2  Characteristics of R32 Refrigerant 
1.  Chemical Characteristics 
R32 is one of the refrigerants used in R410A, has almost no toxicity, and chemically stable compound formed by 
hydrogen, carbon and fluorine. 
 
R32 has short lifetime of 4 to 9 years in case of being released into the atmosphere; therefore, it has smaller 
greenhouse gas effect but has slight inflammability because of the large proportion of hydrogen. 
 
Chemical Characteristic Table of R32, R410A and R22. 
 
  R32  R410A  R22 
Chemical Formula  CH2F2  CH2F2 / CHF2CF3  CHCLF2 
Composition 
(mixture ratio wt.%) 
Single Composition 
R32 / R125A 
Single Composition 
(50 / 50 wt.%) 
Boiling Point (°C)  -51.7  -51.5  -40.8 
Pressure (physical) *1  3.14  3.07  1.94 
Capacity (physical) *2  160  141  100 
COP (physical) *3  95  91  100 
Ozone Depletion Potential (ODP)  0  0  0.055 
Global Warming Potential 
(GWP) *4 
675  2090  1810 
Inflammability *5 
Slightly Inflammable 
(A2L) 
Non-inflammable (A1)  Non-inflammable (A1) 
Toxicity  None  None  None 
 
*1:Physical property of temperature condition 50°C 
*2:Relative value of temperature condition 0/50°C, providing R22=100 
*3:Te/Tc/SC/SH=5/50/3/0°C 
*4:GWP=Global Warming Potential, each figure is based on “4
th
 IPCC4 Report” 
*5:Based on ANSI / ASHRAE std. 34-2010