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Shimadzu AA-7000 Series User Manual

Shimadzu AA-7000 Series
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High-Performance Autosampler
High-Sensitivity Application Data (Analysis of Selenium (Se))
Mix and inject up to four sample types (diluted solution, standard solution,
sample, matrix modifier, etc.). (Of course, unmixed samples can also be injected.)
Select a fluororesin tube or pipette tip as the injection nozzle.
Automatic dilution and re-analysis if the calibration curve concentration is exceeded.
Independent control of the gas flow through the graphite tube during
atomization achieves extremely high-sensitivity measurements.
(Japanese Patent 2067563)
Digital temperature control and electronic gas flow control enhance stability
Combination of a high-sensitivity optical sensor and unique digital temperature control
technology achieves highly accurate temperature control in all temperature regions from
drying to atomization. An electronic flow controller can precisely control the inner gas
flow rate in 0.01 L/min units. These control techniques significantly enhance both the
sensitivity and the data stability.
Example of Automatic Dilution and Re-Analysis
Analysis of cadmium (Cd): The maximum concentration of the calibration curve has been set to 1ppb. At 1.8ppb, the sample of [003] has exceeded the
maximum concentration. As a resultit has been automatically diluted by 4 times and re-measured.
* Depending on the state of the sample, some other combinations may be appropriate.
High-density graphite tube
(P/N 206-50587)
Pyro-coated graphite tube
(P/N 206-50588)
Platform tube
(P/N 206-50887-02)
Selecting the Graphite Tube
Effective for elements that readily form
carbides (Ni, Fe, Cu, Ca, Ti, Si, V, Mo, etc.).
Restricts chemical interference due to
coexisting substances. Effective for the
analysis of environmental samples and
biosamples, such as sea water and
industrial waste.
Can be used for all elements. Especially
effective for low-boiling point elements
(Cd, Pb, Na, K, Zn, Mg, etc.).
Measurement Example Showing High Sensitivity
Analysis of 0 to 5 ppb selenium (Se): Sensitivity is adequate for 1 ppb measurements.
(20 µL injected volume, Pd modifier, pyro-coated graphite tube)
Measurement Example Showing High Stability
Analysis of 0.5 ppb lead (Pb): Approx. 5% relative standard deviation after 5 repeated
measurements is adequate for quantitative analysis.
9

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Shimadzu AA-7000 Series Specifications

General IconGeneral
ModelAA-7000 Series
TypeAtomic Absorption Spectrophotometer
Wavelength Range185 to 900 nm
DetectorPhotomultiplier tube
Flame MethodAir-Acetylene, Nitrous Oxide-Acetylene
MonochromatorCzerny-Turner mounting
Light SourceHollow Cathode Lamp, Deuterium Lamp
Graphite Furnace MethodAvailable
Background CorrectionDeuterium lamp and self-reversal method
Atomization MethodFlame, Graphite Furnace
Graphite Furnace Heating Program20 steps
Safety FeaturesGas leak detector, flame sensor, over-temperature protection
Optical SystemDouble-beam
Sample IntroductionNebulizer for flame, Autosampler for graphite furnace (optional)
Data OutputUSB
Power SupplyAC 100V to 240V, 50/60 Hz
Spectral Bandwidth0.2, 0.5, 1.0, 2.0 nm (automatic switching)

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