PARSTAT 4000 Hardware Manual 
 
 
PARSTAT 4000 Hardware Manual       8 
 
 
Figure 3.  Galvanostat-Mode Block Diagram 
 
1.3. Software 
 
The  PARSTAT  4000  is  fully  compatible  with  the  VersaStudio  software  only.    The 
PARSTAT 4000 will not operate with any other software other than that specified in this 
manual  or  the  most  recent  documentation  available  on  the  web  site 
(http://www.princetonappliedresearch.com). Likewise, the PARSTAT 4000 does not have an 
open command set to allow user programming outside of the VersaStudio software.  
The software is designed specifically to work with Windows XP, Windows 7 and Windows 
8, but it is highly recommended that Windows XP or Windows 7 be used. 
 
1.4. Polarity Convention 
 
The PARSTAT 4000 hardware follows the American polarity convention. (Positive current 
is cathodic; that is, a current is defined as positive if reduction is taking place at the 
working electrode.  Negative current is anodic; that is, a current is defined as negative if 
oxidation  is taking place  at the working  electrode.   If  the  working electrode is  driven 
positive with respect to the equilibrium potential, the resulting current is anodic. If the 
electrode is driven negative with respect to the equilibrium potential, the resulting current 
is cathodic.) 
 
In complex electrochemical systems, there might be more than one equilibrium system.  
Where this is the case, either polarity with respect to the equilibrium potential could give 
rise to anodic or cathodic current, according to the systems’ characteristics. 
1.5. Inspecting Your New Instrument