Nickel
Nickel
Nickel_UniCell_Other_DIMETH_Eng_Ody.fm Page 3 of 4
Accuracy Check
Standard Additions Method (Sample Spike)
1. After reading test results, leave the sample cell (unspiked sample) in the
instrument.
2. Touch
Options. Touch Standard Additions. A summary of the standard
additions procedure will appear.
3. Touch
OK to accept the default values for standard concentration, sample
volume, and spike volumes. Touch
Edit to change these values. After values
are accepted, the unspiked sample reading will appear in the top row. See
Standard Additions in the instrument manual for more information.
4. Prepare three sample spikes. Fill three mixing cylinders with 100 mL of
sample. Use a pipet to add 0.1 mL, 0.2 mL, and 0.3 mL of 1000-mg/L
Ni standard, respectively, to each sample and mix each thoroughly.
5. Transfer 4 mL of each solution into a sample vial and analyze as described in
the procedure. Accept each standard additions reading by touching
Read.
Each addition should reflect approximately 100% recovery.
6. After completing the sequence, touch
Graph to view the best-fit line through
the standard additions data points, accounting for matrix interferences. Touch
View: Fit, then select Ideal Line and touch OK to view the relationship between
the sample spikes and the “Ideal Line” of 100% recovery.
See Section 3.2.2 Standard Additions on page 32 for more information.
Standard Solution Method
1. Prepare a 2.00-mg/L Nickel stock solution by pipetting 0.20 mL of Nickel
Standard Solution, 1000-mg/L as Ni, into a 100-mL volumetric flask. Dilute
to the mark with deionized water. Prepare this solution daily.
2. To adjust the calibration curve using the reading obtained with the
2.00-mg/L working solution, touch
Options on the current program menu.
Touch
Standard Adjust.
3. Touch
On. Touch Adjust to accept the displayed concentration. If an alternate
concentration is used, touch the number in the box to enter the actual
concentration, then touch
OK. Touch Adjust.
See Section 3.2.4 Adjusting the Standard Curve on page 40 for more information.
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