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Agilent Technologies gc/ms series User Manual

Agilent Technologies gc/ms series
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4
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Contaminants & Purities
Contaminants in gases are major contributors to capillary column degradation
and detector noise, and can interfere with chromatographic results. Concentration
of these contaminants vary by the grade of gas.
Hydrocarbons and Halocarbons
Decrease detector sensitivity by increasing detector background noise.
Can also cause baseline drift or wander, contaminant peaks, and noisy
or high offsets of baselines.
Moisture
Can be introduced by improper handling and/or installation of plumbing.
A common cause of column stationary phase degradation.
Can damage instrument.
Oxygen
Most common contaminant.
A common cause of column stationary phase and inlet liner degradation.
Can cause decomposition of labile analytes.
Opportunity for introduction at every fitting present in the gas line or during
use of gas permeable tubing.
Tips & Tools
Gas purifiers should always be
oriented vertically
, not horizontally
.
Purifiers are available in a variety of sizes and configurations to remove common
contaminants like oxygen, moisture, and hydrocarbons. In-line gas purifiers, including
refillable, indicating, S-shaped, and metal body types, are made to remove specific
contaminants. Agilent also offers gas purification systems with removable cartridges.
These systems provide the ability to design the right combination of filters needed
for your application to achieve the proper gas purity.
Gas Purification Systems
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Agilent Technologies gc/ms series Specifications

General IconGeneral
Dynamic Range10^6
Mass Range1050 amu
Mass ResolutionUnit mass resolution
Scan SpeedUp to 12, 500 amu/sec
Ionization ModeElectron Ionization (EI), Chemical Ionization (CI)
Temperature RangeUp to 350°C
Vacuum SystemTurbomolecular Pump
Data SystemAgilent MassHunter

Summary

Gas Management

Gas Purification Systems

Overview of purifiers for removing oxygen, moisture, and hydrocarbons to achieve proper gas purity.

Sample Introduction

Syringe Troubleshooting Guide

Guidance on common syringe problems like bent plungers or needles and their solutions.

Inlets

Split/Splitless Inlets

Overview of the popular split/splitless inlet and troubleshooting common issues like peak broadening.

Cool On-Column Inlets

Advantages of cool on-column injection, sample considerations, and troubleshooting tips.

Programmed Temperature Vaporizer (PTV) Inlets

Benefits, practices, and rationales for PTV inlets, offering flexibility in sample introduction.

Detectors

Flame Ionization Detector (FID)

Routine maintenance, typical problems, and troubleshooting for the FID.

Electron Capture Detector (ECD)

Liner selection, makeup gas adapter maintenance, thermal cleaning, and leak testing for ECD.

Thermal Conductivity Detector (TCD)

Filament maintenance, lifetime extension, cell contamination, and solvent flush procedures for TCD.

Flame Photometric Detector (FPD)

Recommended gas flows, maintenance, contamination, and ignition problems for the FPD.

GC/MS Systems

Maintaining Mass Selective Detectors (MSD)

Benefits of maintaining GC/MSD systems, including reduced downtime and longer lifespan.

MSD Contamination

Identifying contamination sources in the GC and MSD, and common contaminants and their origins.

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