Varian Solid-State NMR - Page 5

Table of Contents
5 VNMR 6.1C User Guide: Solid-State NMR 01-999162-00 C0402
Chapter 5. Solid-State NMR Accessories ...................................................... 72
5.1 Pneumatics/Tachometer Box ...................................................................................... 72
5.2 Rotor Synchronization Operation ............................................................................... 72
5.3 Rotor Speed Controller Accessory Operation ............................................................ 76
5.4 Variable Temperature Operation with Solids .............................................................. 78
Chapter 6. Solid-State NMR Experiments ..................................................... 80
6.1 XPOLAR—Cross-Polarization, UNITY .................................................................... 81
6.2 XPOLAR1—Cross-Polarization ................................................................................. 85
6.3 XPWXCAL—Observe-Pulse Calibration with Cross-Polarization ............................ 87
6.4 XNOESYSYNC—Rotor Sync Solids Sequence for Exchange .................................. 89
6.5 MASEXCH1—Phase-Sensitive Rotor Sync Sequence for Exchange ........................ 90
6.6 HETCORCP1—Solid-State HETCOR ....................................................................... 92
6.7 WISE1—Two-Dimensional Proton Wideline Separation ........................................... 93
6.8 XPOLWFG1—Cross-Polarization with Programmed Decoupling ............................ 93
6.9 XPOLXMOD1—Waveform Modulated Cross-Polarization ...................................... 95
6.10 VACP—Variable Amplitude Cross-Polarization ...................................................... 97
6.11 XPOLEDIT1—Solids Spectral Editing .................................................................... 98
6.12 3QMAS1—Triple-Quantum 2D for Quadrupole Nuclei .......................................... 99
6.13 PASS1—2D Sideband Separation for CP/MAS ..................................................... 101
6.14 CPCS—Cross-Polarization with Proton Chemical Shift Selection ........................ 102
6.15 CPCOSYPS—Cross-Polarization Phase-Sensitive COSY ..................................... 103
6.16 CPNOESYPS—Cross-Polarization Phase-Sensitive NOESY ................................ 104
6.17 R2SELPULS1—Rotation Resonance with Selective Inversion ............................. 106
6.18 DIPSHFT1—Separated Local Field Spectroscopy ................................................. 108
6.19 SEDRA2—Simple Excitation of Dephasing Rotational-Echo Amplitudes ........... 109
6.20 REDOR1—Rotational Echo Double Resonance .................................................... 111
6.21 DOUBLECP1—Double Cross-Polarization ........................................................... 113
6.22 T1CP1—T
1
Measurement with Cross-Polarization ................................................ 115
6.23 HAHNCP1—Spin 1/2 Echo Sequence with CP ..................................................... 116
6.24 SSECHO1—Solid-State Echo Sequence for Wideline Solids ................................ 117
6.25 WLEXCH1—Wideline Solids Exchange ............................................................... 119
6.26 HS90—90-Degree° Phase Shift Accuracy .............................................................. 121
6.27 MREVCS—Multiple Pulse Chemical-Shift Selective Spin Diffusion ................... 122
6.28 MQ_SOLIDS—Multiple-Quantum Solids ............................................................. 123
6.29 SPINDIFF—Spin Diffusion in Solids .................................................................... 124
6.30 FASTACQ—Multinuclear Fast Acquisition ........................................................... 124
6.31 NUTATE—Solids 2D Nutation .............................................................................. 125
Index ................................................................................................................ 128