82 Advanced User Guide
5 Detectors
µECD gas flows
µECD linearity
The µECD response factor versus concentration curve is linear
for four orders of magnitude or more (linear dynamic range =
10
4
or higher) for a broad range of compounds. You should still
run a calibration curve on your samples to find the limits of the
linear range for your materials.
µECD detector gas
The µECD operates with either nitrogen or argon/methane as
the makeup and anode gas. Purity is critical; gases must exceed
99.9995% purity.
Because of the high detector sensitivity, carrier and makeup gas
must be dry and oxygen-free. Moisture, chemical, and oxygen
traps in good condition should be installed in carrier and
makeup gas supply lines. Do not use plastic (including PTFE)
tubing, plastic-bodied traps, or O-ring seals.
Column
Vent
63
Ni
Capillary adapter
PS = Pressure Sensor
PSPS
EPC Module
Anode purge
Makeup
Frit Frit
PS
Valve
Frit
Valve
Frit
Valve
Frit