AO2000 CONTINUOUS GAS ANALYZERS  |  OI/AO2000-EN REV. B  237
 
 
 
Caldos25, Caldos27: Substitute gas calibration 
Example 
Substitute gas calibration in the Caldos25 and Caldos27 is described using 
the example of "CO
2
 measurement in flue gas". 
CO
2
 measurement in flue gas 
The composition of the various combustion products in the sample gas is 
known
2
 measurements of flue gas from single-component firings. The flue 
gas out of the cooler primarily contains CO
 2
, O
2
, N
2
 and Ar. CO
2
 cannot be 
measured in mixed-firing flue gases. 
Test gases 
The following table shows test gases for the calibration of the 0 to 20 vol.% 
of CO
2
 measurement range: 
Fuel  Test gas composition in vol.% for 
  Zero  Middle concentration  Span 
    CO
2
 O
2
 N
2
 Ar  CO
2
 O
2
 N
2
 Ar 
Gas Air  10 3 86 1  20 – 79 1 
Oil Air  10 8 81 1 20 – 79 1 
Coal  Air  10 10 79 1  20 –  79 1 
Calibration with substitute gas 
Since the test gases in this table are not available everywhere, the analyzer 
module can be factory-set for calibration with a substitute gas. In this case 
an additional measurement range is calibrated for 0 to 20 vol.% of CO
2
 in N
2
 
(N
2
 and CO
2
/N
2
 mixtures are available practically everywhere). 
Measurement ranges 
 
Component 1  CO
2
 in flue gas  Meas. range 1  0 to 10 vol.% 
        Meas. range 2  0 to 20 vol.% 
Component 2  CO
2
 in N
2
 (substitute gas)  Meas. range 1  0 to 20 vol.% 
Calibration data 
 
Calibration method  Substitute gas calibration 
Zero component  Component 1  Meas. range 1 or 
    Component 2  Meas. range 1 
Span component  Component 2  Meas. range 1 
Calibration 
•  Calibrate zero with air (component 1) or N
2
 (component 2). 
•  Calibrate span with test gas 18 vol.% CO
2
 in N
2
. 
Other measurement tasks 
For other measurement tasks select the test gases and measurement ranges 
in a similar manner according to the sample gas composition.