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Malvern Mastersizer 3000 User Manual

Malvern Mastersizer 3000
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Chapter 5 Viewing measurement results
Page 5-16 MAN 0474
Concentration at different obscurations
This advice gives an approximate idea of the obscuration ranges to use during a
measurement.
It is possible to convert the obscuration limits into an equivalent volume concen-
tration but there is a strong size dependence that makes it difficult to use the data at
the time of measurement. The relative volume concentrations of monomodal (sin-
gle sized) particles that would give a certain obscuration is illustrated below. The
actual curves differ according to the presentation being used. It will be clear that
there is a size dependence; an obscuration of 30% means a widely varying volume
concentration dependent on size.
Concentration at different obscurations
Calculated for glass beads in water (n=1.54 +i0) in water
In the more realistic situation of a polydisperse (or multimodal) sample it is not
possible to provide simple graphical correlations of volume concentrations and
obscuration. The system calculates concentration, however, using the size distribu-
tion result and the obscuration.
For a polydisperse sample the curve of the above figure can be used if the
Surface Weighted Mean (D[3, 2]) of the material is taken as single size.
Volume-based results
The first, and probably most important, point to remember in interpreting results
is that the fundamental size distribution derived by this technique is volume-based.
This means that when a result indicates, for example, that 11% of the distribution is

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Malvern Mastersizer 3000 Specifications

General IconGeneral
Measurement principleLaser diffraction
Blue laser wavelength470 nm
Sample dispersion optionsWet and dry dispersion
Data acquisition rate10 kHz
Particle size range0.01 to 3500 microns
Laser typeHe-Ne and solid state
AccuracyBetter than 1%
RepeatabilityBetter than 0.5%
TechnologyMie and Fraunhofer theories
Sample dispersion unitsHydro MV, Hydro LV, Aero S
Optical modelMie theory
Power requirements100-240 V, 50/60 Hz
Detector arrangementLog-spaced array

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