5. Sensors and optical system ABL90 FLEX reference manual
5-24
Measuring principle of the pCO
2
sensor
The electrode chain (or electrical circuit) set up to measure pCO
2
is illustrated in
the following diagram:
The electrode chain describes an electrical circuit consisting of the following:
Item Part Description
1 Voltmeter Measures the voltage potential in the
circuit.
2 pH electrode Provides electrical connection to the
voltmeter
3 Electrolyte solution Medium for connection
4 Internal reference electrode
(Ag/AgCl)
Provides electrical connection to the
voltmeter
The potential differences at all the junctions in the electrode chain are known
and constant, except that at the pH-sensitive membrane. (See the section
pH
and electrolyte sensors
for a full explanation.)
The potential difference at the pH-sensitive membrane depends on the pH of the
electrolyte solution, which in turn depends on the CO
2
content of the sample.
This is explained in the measuring process below.
Electrode chain
Parts and
description
Electrode chain
potential