Bruker BioSpin Solid State NMR User Manual

Version
Bruker BioSpin
think forward
NMR Spectroscopy
Solid State NMR
002
AVANCE Solids
User Manual

Bruker BioSpin Solid State NMR Specifications

General

Probe Types	static
Digital Receivers	High-resolution, multi-channel digital receivers
Software	TopSpin
Spinning Speed	Up to 110 kHz for MAS probes
Nuclei	1H, 13C, 15N, 17O, 19F, 23Na, 27Al, 29Si, 31P

Summary

1 Introduction

1.2 Safety Issues

Provides essential safety information and warnings for operating the instrument and its components.

3 General Hardware Setup

3.1 Connections to the Preamplifier

Details the physical connections between the spectrometer and preamplifiers.

3.7 Probe Setup, Operations, Probe Modifiers

Covers probe setup, operational procedures, and modifications for optimal performance.

4 Basic Setup Procedures

4.2 Setting the Magic Angle on KBr

Describes how to set the magic angle using KBr, a crucial step for MAS experiments.

4.3 Calibrating 1H Pulses on Adamantane

Step-by-step guide for calibrating proton pulses using Adamantane for optimal RF performance.

4.4 Calibrating 13C Pulses on Adamantane and Shimming the Probe

Details calibrating carbon pulses and shimming the probe for accurate 13C NMR experiments.

5 Decoupling Techniques

7 Basic CP-MAS Experiments

7.1 Pulse Calibration with CP

Details pulse calibration procedures for 13C pulses after cross polarization.

8 FSLG-HETCOR

8.2 Setting up FSLG HETCOR

Provides detailed instructions for setting up the FSLG HETCOR experiment.

11 Proton Driven Spin Diffusion (PDSD)

14 Symmetry Based Recoupling

14.2.2 Setup for the Recoupling Experiment

Details the specific setup steps for recoupling experiments.

15 PISEMA

15.2 Setup

Explains the setup for the PISEMA experiment, including sample preparation and parameter adjustments.

16 Relaxation Measurements

16.2.2 The CP Inversion Recovery Experiment

Details the CP inversion recovery experiment for measuring T1 values.

17 Basic MQ-MAS

17.3.1 Setting Up the Experiment

Guides through the initial setup of the MQMAS experiment, including pulse calibration.

18 MQ-MAS: Sensitivity Enhancement

18.2 Implementation of DFS into MQMAS Experiments

Explains how to implement Double Frequency Sweep (DFS) for improved MQMAS sensitivity.

18.2.1 Optimization of the Double Frequency Sweep (DFS)

19 STMAS

19.3 Experiment Setup

20 Double-CP

20.2 Double CP Experiment Setup

20.2.1 Double CP 2D Experiment Setup

20.2.3 Setup of the Double CP Experiment

21 CRAMPS: General

22 CRAMPS 1D

22.5 Parameter Settings for PMLG and DUMBO

23 Modified W-PMLG

23.4 Parameter Settings for PMLG and DUMBO

24 CRAMPS 2D